^^^How do I do that Serge? All new to me etc
Almost impossible without some instrumentation, but you can get away with using a multimeter, which can be bought from Maplins for around a tenner.
Play a steady tone from the source and measure the level coming out of the DAC and the level coming out of the Mac mini, and adjust the volume level so that the two match to within about 1%.
This assumes that the MAC mini's volume control for the analogue output doesn't also affect the digital output. If it does, then it's going to be a lot more complicated.
You can create steady tones using Audacity, or there are lots on YouTube that you just play. I suggest a frequency of somewhere between 300-700 Hz, but even 1 kHz should be OK. The accuracy of the multimeter will be poor, as it's designed to measure mains at 50 or 60Hz, but accuracy isn't important as what you're doing here is matching two levels, so whatever the inaccuracy is for one, it will be the same for the other.
Then, once the levels are matched, without touching the volume control(s) on the DAC or MAC, plug the MAC and DAC into two inputs on your amp. You need to make sure that both inputs have the same sensitivity, but normally two line inputs will have. Then listen to some music, getting someone else to switch between MAC and DAC without telling you which is which. Firstly, see if you can hear a difference, then try and state a preference.
I would then repeat the test using the amplifier inputs the other way round (MAC for DAC) just in case the amp does have slightly different sensitivities. See if you get the same results.
My expectation is that you won't reliably be able to hear any difference between MAC and DAC when listened to blind, even though you may have a clear preference when you know what you're listening to.
S.