The differences noted from leaning forwards and back could either be due to the presence of the sofa back, or the change of where your head is in relation to the room (a room mode effect) or a combination. I'm about to replace my sofa but I am deliberately avoiding anything with a high back for acoustic reasons, but I don't have any personal experience with a high back sofa to comment on.
I think we just have a different idea of what a typically sized UK room may be
. The room you have most of your panels in I would consider to be huge!
I'll be honest I'm sceptical how useful diffusion on the front wall (where TVs go) actually is, given the way standardly designed speakers predominantly radiate higher frequencies in the forward direction. The front wall tends to be about the last boundary on which acoustic treatments are suggested for this reason. I did try putting a panel immediately in front of my TV once just out of interest and from memory there was virtually no measurable difference at the listening position. I've just had a quick look and can't find the actual data to share though I'm afraid. I really don't think having a TV where I do is any significant compromise at all though, and anyway it's not going anywhere
. Well, until it's replaced with a larger TV anyway!